Skip to main content

2% Nital

General Purpose

Composition

2% Nitric Acid in Ethanol

2%

Method

Immersion

Time

5–30 s

Alternative Names

2% Nitric AcidNital 2%

Tags

carbon-steellow-alloy-steelcast-irongeneral-purpose

Reveals

Ferrite grain boundaries; pearlite (darkened by cementite-ferrite interface attack); bainite; mild contrast on martensite

Typical Results

The workhorse etchant for carbon and low-alloy steels. Darkens pearlite, leaves ferrite light, and reveals ferrite grain boundaries in annealed and normalized structures. Mild attack, appropriate as the first-try etchant on unknown steel.

Application Method

Method:Immersion
Typical Time:5–30 s

Preparation Notes

Mix 2 ml concentrated nitric acid (HNO₃) with 98 ml ethanol (95% or absolute). Add acid to ethanol slowly with stirring. Store in glass bottle.

Application Notes

Immerse the polished surface 5–30 s at room temperature. Swab gently if attack is uneven. Rinse with ethanol, then water; air-dry.

Troubleshooting

Over-etch flattens ferrite contrast and darkens the whole surface; repolish lightly with 1 µm diamond and re-etch shorter. Under-etch on bainite or fine pearlite; step up to 3% Nital or extend to 30 s.

Storage Notes

Tightly capped amber glass at room temperature; vent occasionally (NOx evolution). Stable 3–6 months.

Alternative Etchants

  • 3% Nital
  • 4% Picral
  • Klemm's Reagent

Similar Etchants

  • 3% Nital
  • 5% Nital

ASTM References

ASTM E407 #74